I’ve recently passed the Microsoft 70-483 “Programming in C#” certification which is one of the entry point into the .Net and WinRT developers certification cycles.
To be well prepared I’ve read the two books entirely dedicated to this certification : MCSD Certification Toolkit (Exam 70-483): Programming in C# and Exam Ref 70-483: Programming in C#.
I strongly recommend you read both of them if you intend to pass the certification.
Indeed both have been my main material to prepare for the certification and they have perfectly done the job.
This article is a complete review of MCSD Certification Toolkit (Exam 70-483): Programming in C#.
This is the first book you should read because I think this is the one that will best prepare you to get the certification, but paradoxically the worst from a technical point of view, and you will quickly understand why.